[Ir(dtbbpy)(ppy)2][PF6] - Names and Identifiers
Name | (4,4'-Di-tert-butyl-2,2'-bipyridine)bis[(2-pyridinyl)phenyl]iridium(III) Hexafluorophosphate
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Synonyms | [Ir(dtbbpy)(ppy) Ir(ppy)2(dtbbpy)PF6 [Ir(dtbbpy)(ppy)2][PF6] (4,4'-Di-tert-butyl-2,2'-bipyridine)bis[(2-pyridinyl)phenyl]iridium(III) Hexafluorophosphate (4,4'-Di-tert-butyl-2,2'-bipyridine)di[(2-pyridinyl-κN)phenyl-κC]iridium hexafluorophosphate [4,4'-Bis(tert-butyl)-2,2'-bipyridine]bis[2-(2-pyridinyl)phenyl]iridium(III) hexafluorophosphate
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CAS | 676525-77-2
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[Ir(dtbbpy)(ppy)2][PF6] - Physico-chemical Properties
Molecular Formula | C40H40F6IrN4P
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Molar Mass | 913.97 |
Appearance | crystal |
Color | yellow |
Maximum wavelength(λmax) | ['380nm(CH2Cl2)(lit.)'] |
Storage Condition | 2-8°C |
[Ir(dtbbpy)(ppy)2][PF6] - Risk and Safety
Risk Codes | 36/37/38 - Irritating to eyes, respiratory system and skin.
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Safety Description | 26 - In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
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WGK Germany | 3 |
TSCA | No |
[Ir(dtbbpy)(ppy)2][PF6] - Introduction
(4,4 '-Di-tert-butyl-2,2'-bipyridine)bis[(2-pyridinyl)phenyl]iridium(III) Hexafluorophosphate is an important iridium complex. The general properties of this compound are as follows:
1. appearance: usually yellow solid.
2. solubility: soluble in organic solvents, such as ether and dichloromethane, insoluble in water.
3. Melting point: about 260°C.
4. stability: stable in the air, but sensitive to light.
The main uses of (4,4 '-Di-tert-butyl-2,2'-bipyridine)bis[(2-pyridinyl)phenyl]iridium(III) Hexafluorophosphate include:
1. Optoelectronic devices: It can be used as a light-emitting material in organic light-emitting diodes (OLED), and its fluorescent properties make it an important component for efficient energy conversion.
2. Catalyst: This compound can be used as a catalyst for redox reactions and amination reactions, and has important applications in organic synthesis.
3. Photochemical materials: can be used as photocatalyst, photosensitive dyes and photoelectric sensors.
The method of preparing (4,4 '-Di-tert-butyl-2,2'-bipyridine)bis[(2-pyridinyl)phenyl]iridium(III) Hexafluorophosphate generally involves the following steps:
1. Iridium (III) chloride reacts with excess (4,4 '-di-tert-butyl-2, 2'-bipyridine) and 2-pyridylbenzene to generate the corresponding complex.
2. using hexafluorophosphate salt chemical reaction, the complex is converted to hexafluorophosphate salt form.
Regarding safety information, this compound needs to be handled with caution because iridium is a toxic metal. Here are some safety considerations:
1. Wear appropriate personal protective equipment, including protective glasses and chemical gloves.
2. Avoid contact with skin and inhalation of dust during operation.
3. Operate in a well-ventilated laboratory to avoid the accumulation of volatiles.
4. storage should pay attention to avoid fire and high temperature.
When using this compound, be sure to refer to the chemical safety data sheet (SDS) and operating manual, and follow the correct operating procedures and safety measures.
Last Update:2024-04-09 20:02:46